The second argument for PIO_Configure is the list size,
which can be determined using the macro PIO_LISTSIZE.
You should pass the list (which is an array of pins) to it.
Refrain from passing the ADDRESS of the list to it, otherwise
the pin configuration is never applied and you find yourself
debugging for 3 days.
In other words:
It's working, don't touch it or it will break again!
When the SIM card adapter, which is usually plugged into a phone,
is plugged into a CCID reader instead, the CCID reader triggers
the reset line of the RST line and therefore a PIO interrupt.
The reader then waits for an ATR from the smartcard,
which should be send next.